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Non-repeatable- Tohjo Falls (Western ledge behind waterfalls)- Ruins of Alph (Hidden room in lower right entrance 2)- Player’s mom (Once an unknown amount of money has been saved)
Repeatable- Mt. Moon Square (Mondays at night)- Bug-Catching Contest (post-National Dex, first place)- Pokeathlon Dome (3000 points, Monday/Wednesday)- Pickup (starting at Level 41)- Wild Clefairy, Clefable, Lunatone (5%)
Non-repeatable- National Park (Northeast cliff behind the fence)
Repeatable- Route 14 (Gift from Bird Keeper Josh if player has his phone number)- Bug-Catching Contest (post-National Dex, first place)- Pokeathlon Dome (3000 points, Sunday/Monday/Wednesday/Thursday/Saturday)
All can be bought by points from the Pokeathlon, in the Pokeathlon shop.
Well you can’t go underground in SS.Although like charizard said all of them can be bought from the pokeathon’s shop.