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Tentacruel @ Black SludgeAbility: Rain DishEVs: 252 HP / 32 Def / 224 SpDCalm Nature- Toxic Spikes- Rapid Spin- Scald- Ice Beam
This is a good support setup for Tentacruel - perfect for Toxic Spikes. His SpD bulk makes him one of the only viable Pokemon to set up Toxic Spikes. Rapid Spin for set up coverage and Scald for damage output and 30% burn chance.
The Fastest would be Scolipede.with 118 base speed and speed boost its nearly guarenteed to setup toxic spikes.
Scolipede@ Focus SashSpeed Boost252 speed 252 atk 4 hpToxic spikesProtectPoison JabXscissors
This set allows it to setup spikes and then do some good damage(possibly sweep)also you can replace something for Baton Pass and give a new poke some great speed if you prefer.