I don’t want to know how to switch the charged attack, but to have two options at once while battling.
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Source:Bulbapedia
The player can also spend Stardust and Candy to teach a Pokémon asecond Charged Attack. Upon evolution, both Charged Attack will berandomly reselected. Caterpie, Metapod, Weedle, Kakuna, Magikarp,Ditto, Wynaut, Wobbuffet, Smeargle, Wurmple, Silcoon, Cascoon,Taillow, Feebas, Beldum and Kricketot cannot learn a second ChargedAttack.The cost varies depending on the Pokémon species and largelycorresponds with the distance needed to walk for a Buddy Pokémon tofind a Candy. In addition Shadow Pokémon, compared to their baseforms, requires 1.2× Stardust and Candy to learn a second ChargedAttack, while Purified Pokémon require 0.8× the base amounts.
The option to teach the second charged move is on the lower part of the Pokémon’s summary screen. It can cost quite a lot of stardust and candies dpending of the Pokémon.
Hope I helped!