On X/Y!
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Espurr learns Fake Out at Level 19.
[Source][1]
You can also substitute Espurr with the following Pokemon if they are male and know Fake Out:
Meowth, Persian, Nuzleaf, Shiftry, Skitty, Delcatty, Glameow, Purugly, Purrloin, Liepard, Mienfoo, Mienshao, Meowstic(M or F), Pikachu, Raichu, Seel, Dewgong, Aipom, Delibird, Spinda, Kecleon, Chimchar, Monferno, Infernape, Ambipom, Buneary, Lopunny, Scraggy, Scrafty, Smeargle[1]:http://www.serebii.net/pokedex-xy/egg/461.shtml#fakeout
You can breed it with any of the following males that knows Fake Out already:MeowthPersianTyrogueLombreNuzleafMakuhitaHariyamaSkittyDelcattySableyeGlameowPurugly
Source