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Metapod, Kakuna, Pineco, Silcoon, Cascoon, Shedinja, Spewpa and Cosmoem cannot eat Poke Beans.Source
If my memory serves me right, I do believe that Cosmoem doesn’t eat Poke Beans.
EDIT: It doesn’t!
I do not believe so.I wish I could give you a more definite answer, but it would take a lot of testing. I tested Magnemite, Diglett, Roggenrola, and poliwhirl (four Pokemon without mouths) and they were all able to eat pokebeans, so I would therefore assume that all Pokemon can eat pokebeans.
~Rio
Ive tried pineco, and it cant eat any poke beans, You can tell when you go in poke refresh, and when you try to select another Pokemon to feed/pet, youll see that the ‘fullness’ bar will be fade if the Pokemon cant eat any beans